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Nonmetal

Adapted from Wikipedia · Discoverer experience

A close-up of a sulfur sample, showcasing its bright yellow color against a white background.

Nonmetals are special kinds of elements that are not metals. They have different properties from metals and are important in many things we see and use every day. Some nonmetals, like hydrogen and helium, are gases that are very light and can float. Others, like iodine, are shiny and solid. Nonmetals usually don't conduct heat or electricity very well, which makes them useful in many technologies.

There are seventeen elements that are widely known as nonmetals. These include gases like hydrogen and helium, and solids like carbon and sulfur. Together, hydrogen and helium make up about 98% of everything we can see in the universe. On Earth, nonmetals are very important because they are part of the air we breathe, the water we drink, and even the ground we walk on.

Nonmetals are used in many industries. For example, they are important in making electronics, helping engines burn fuel, and creating products that reduce friction. Scientists have been studying nonmetals for many years, and they continue to find new ways to use them in our everyday lives.

Definition and applicable elements

Unless otherwise noted, this article describes the stable form of an element at standard temperature and pressure (STP).

Nonmetallic chemical elements are elements that do not have the usual properties of metals, such as shininess, flexibility, or the ability to conduct heat and electricity well. Because of how their electrons are arranged band structure, they behave differently from metals.

While arsenic (here sealed in a container to prevent tarnishing) has a shiny appearance and is a reasonable conductor of heat and electricity, it is soft and brittle and its chemistry is predominately nonmetallic.

Fourteen elements are almost always recognized as nonmetals:

Three more are often considered nonmetals, but some sources group them with elements called "metalloids":

Some elements usually called metalloids can also be counted as nonmetals by some scientists:

Together, nonmetals make up about 15–20% of all known elements.

General properties

Electronegativity values of the group 16 chalcogen elements showing a W-shaped alternation or secondary periodicity going down the group

Nonmetals are elements that do not have typical metallic properties. They can be gases, like hydrogen, or solids, like carbon, and they often look different from metals. Some nonmetals are colorless, while others are colorful or even shiny.

Most nonmetals are gases or solids at normal temperatures. They are usually lighter and do not conduct heat or electricity well. Their shapes and forms can vary a lot, from soft and pliable to hard and brittle.

Some general physical differences
between elemental metals and nonmetals
AspectMetalsNonmetals
Appearance
and form
Shiny if freshly prepared
or fractured; few colored;
all but one solid
Shiny, colored or
transparent; all but
one solid or gaseous
DensityOften higherOften lower
PlasticityMostly malleable
and ductile
Often brittle solids
Electrical
conductivity
GoodPoor to good
Electronic
structure
Metal or semimetalicSemimetal,
semiconductor,
or insulator
Some general chemistry-based
differences between metals and nonmetals
AspectMetalsNonmetals
ReactivityWide range: very reactive to noble
OxideslowerBasicAcidic; never basic
higherIncreasingly acidic
Compounds
with metals
AlloysCovalent or Ionic
Ionization energyLow to highModerate to very high
ElectronegativityLow to highModerate to very high

Types

Different ways to group nonmetals exist, with some grouping them into just two types and others into up to seven. For example, one common way to group them includes noble gases, halogens, and other nonmetals. Another way looks at seven color groups on a special chart that include nonmetals.

There are three main types of nonmetals starting on the right side of the periodic table:

  • The noble gases — helium, neon, argon, krypton, xenon, and radon. These are not very reactive.
  • The halogen nonmetals — fluorine, chlorine, bromine, and iodine. These are very reactive.
  • The "unclassified nonmetals" — hydrogen, carbon, nitrogen, oxygen, phosphorus, sulfur, and selenium. These have mixed reactivity and don’t have a common name.

Some people also consider metalloids, such as boron and silicon, as a fourth group. These elements have properties of both metals and nonmetals, making their classification tricky.

Noble gases

Main article: Noble gas

Six nonmetals are noble gases: helium, neon, argon, krypton, xenon, and radon. They are found in the far right column of the periodic table and are called noble gases because they hardly react with other elements. They are colorless, smellless, and do not catch fire. Because their outer electron shells are full, noble gases melt and boil at very low temperatures.

Halogen nonmetals

Main article: Halogen

The halogen nonmetals — fluorine, chlorine, bromine, and iodine — are very reactive. They easily lose or gain electrons and have strong pulling power on other elements. They usually form compounds with metals, unlike most other nonmetals.

Unclassified nonmetals

Hydrogen acts sometimes like a metal and sometimes like a nonmetal. For example, it can form bonds like a metal in water or like a nonmetal in hydrochloric acid. These nonmetals are less reactive than halogens and can be found in nature. They can form special compounds with metals and often bond to themselves, especially in solid forms.

Group (1, 13−18)Period
131415161/1718(1−6)
HHe1
BCNOFNe2
SiPSClAr3
GeAsSeBrKr4
SbTeIXe5
Rn6

Abundance, extraction, and uses

The elements in the universe come from processes in stars and radioactive changes. Some nonmetal elements, like the noble gases, are less common in Earth's air than we might expect. Scientists study these differences to learn more about our planet.

Several important nonmetals make up most of Earth’s surface, air, water, and living things. These include hydrogen, carbon, nitrogen, oxygen, and silicon. They help form the rocks of Earth’s crust and are key for life.

We get many nonmetals from natural gas, air, seawater, and mining. For example, nitrogen and oxygen are taken from air, and chlorine comes from seawater. Nonmetals have many uses: hydrogen can help power clean energy, carbon is in diamonds and graphite, oxygen helps us breathe and powers fires, and silicon is used in many electronic devices. Noble gases like helium and argon have special uses, such as keeping things very cold or stopping fires safely.

Group (1, 13−18)Period
131415161/1718(1−6)
HHe1
BCNOFNe2
SiPSClAr3
GeAsSeBrKr4
SbTeIXe5
Rn6

Taxonomical history

Medieval thinkers mainly studied metals and rarely looked into nonmetallic minerals.

French chemist Antoine Lavoisier made big changes in chemistry. In 1789, he created the first modern list of chemical elements. He grouped the 33 known elements into four types: gases, metals, nonmetals, and earths. His work was very important and was published in many languages.

Later scientists added new ways to sort elements. In 1802, the word "metalloids" was used for elements that had some properties of metals and some of nonmetals. By the mid-1800s, scientists like Alphonse Dupasquier organized nonmetals into groups such as organogens (oxygen, nitrogen, hydrogen, carbon) and chloroides (fluorine, chlorine, bromine, iodine). These early groupings helped shape how we understand elements today.

Comparison of selected properties

See also § Physical

Physical properties are shown in a simple list, making it easy to see how different elements behave.

See also § Chemical

Chemical properties are shown from general traits to more detailed points.

† Hydrogen can also form special mixtures with metals
‡ The words low, moderate, high, and very high are used to describe values in the table.

PropertyElement type
MetalsMetalloidsUnc. nonmetalsHalogen nonmetalsNoble gases
General physical appearancelustrouslustrous
◇ lustrous: carbon, phosphorus, selenium
◇ colored: sulfur
◇ colorless: hydrogen, nitrogen, oxygen
◇ lustrous: iodine
◇ colored: fluorine, chlorine, bromine
colorless
Form and densitysolid
(Hg liquid)
solidsolid or gassolid or gas
(bromine liquid)
gas
often high density such as iron, lead, tungstenlow to moderately high densitylow densitylow densitylow density
some light metals including beryllium, magnesium, aluminiumall lighter than ironhydrogen, nitrogen lighter than airhelium, neon lighter than air
Plasticitymostly malleable and ductileoften brittlephosphorus, sulfur, selenium, brittleiodine brittlenot applicable
Electrical conductivitygood
◇ moderate: boron, silicon, germanium, tellurium
◇ good: arsenic, antimony
◇ poor: hydrogen, nitrogen, oxygen, sulfur
◇ moderate: phosphorus, selenium
◇ good: carbon
◇ poor: fluorine, chlorine, bromine
◇ moderate: I
poor
Electronic structuremetal (beryllium, strontium, α-tin, ytterbium, bismuth are semimetals)semimetal (arsenic, antimony) or semiconductor
◇ semimetal: carbon
◇ semiconductor: phosphorus
◇ insulator: hydrogen, nitrogen, oxygen, sulfur
semiconductor (I) or insulatorinsulator
PropertyElement type
MetalsMetalloidsUnc. nonmetalsHalogen nonmetalsNoble gases
General chemical behavior
◇ strong to weakly metallic
noble metals are relatively inert
weakly nonmetallicmoderately nonmetallicstrongly nonmetallic
◇ inert to nonmetallic
◇ radon shows some cationic behavior
Oxidesbasic; some amphoteric or acidicamphoteric or weakly acidicacidic or neutralacidicmetastable XeO3 is acidic; stable XeO4 strongly so
few glass formersall glass formerssome glass formersno glass formers reportedno glass formers reported
ionic, polymeric, layer, chain, and molecular structurespolymeric in structure
◇ mostly molecular
◇ carbon, phosphorus, sulfur, selenium have 1+ polymeric forms
◇ mostly molecular
◇ iodine has a polymeric form, I2O5
◇ mostly molecular
XeO2 is polymeric
Compounds with metalsalloys or intermetallic compoundstend to form alloys or intermetallic compounds
◇ salt-like to covalent or metallic: hydrogen†, carbon, nitrogen, phosphorus, sulfur, selenium
◇ mainly ionic: oxygen
mainly ionicsimple compounds at STP not known
Ionization energy (kJ mol−1)low to highmoderatemoderate to highhighhigh to very high
376 to 1,007762 to 947941 to 1,4021,008 to 1,6811,037 to 2,372
average 643average 833average 1,152average 1,270average 1,589
Electronegativity (Pauling)low to highmoderatemoderate to highhighhigh (radon) to very high
0.7 to 2.541.9 to 2.182.19 to 3.442.66 to 3.98ca. 2.43 to 4.7
average 1.5average 2.05average 2.65average 3.19average 3.3

Images

A colorful chart showing which elements on the periodic table are classified as nonmetals, using different colors to indicate their categories.
A scientific sample of boron, an element found in nature, shown as small crystalline chunks.
A scientist tests liquid oxygen in a beaker, an important substance used to provide oxygen for pilots flying at high altitudes.
Close-up of iodine crystals, showcasing their unique purple color and crystalline structure.
A special acrylic cube containing liquefied xenon gas, used for scientific study and collection.
A sparkling diamond crystal from South Africa, showing a rare and impressive natural shape.
A sample of graphite, a natural mineral used in pencils and other applications.
A vial containing liquid bromine, showing its red-brown vapor, used in chemistry to study elements and their properties.
A scientific image showing crystallized Buckminsterfullerene, also known as Buckyballs, a form of carbon molecules studied in chemistry.
A shiny piece of graphite, a type of carbon, from a farm in New Hampshire.

Related articles

This article is a child-friendly adaptation of the Wikipedia article on Nonmetal, available under CC BY-SA 4.0.

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