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Iron

Adapted from Wikipedia · Discoverer experience

A close-up of pure iron chips and a perfectly formed iron cube, demonstrating the physical appearance of the element iron.

Iron is a chemical element with the symbol Fe, coming from the Latin word ferrum. It is a strong metal and one of the most common elements on Earth, making up much of our planet's outer and inner core. Because it is so plentiful, iron has been very important throughout human history.

People learned how to work with iron around the year 1200 BC, which marked the beginning of the Iron Age. During this time, iron tools and weapons began to replace those made from copper alloys. Today, iron is used to make many everyday materials such as steel, stainless steel, and cast iron, making it a key part of our modern world.

Pure iron has a silvery-gray color, but it easily reacts with oxygen and water to form rust. This rust flakes off and allows more iron to corrode, which is why many iron objects eventually deteriorate. In living things, iron is vital—it helps carry oxygen in our blood through a protein called hemoglobin and stores oxygen in muscles with another protein called myoglobin. Our bodies need a small amount of iron from food to stay healthy.

Characteristics

Iron is a special kind of metal that comes from the Latin word "ferrum." It has the symbol Fe and the number 26, which tells us how many tiny parts called protons are in its atoms. Iron is very common and makes up a big part of the Earth we live on.

Iron can change its shape depending on how it is treated. When it cools down from being melted, it forms different patterns of atoms. One kind, called alpha-iron, is found in ordinary conditions. Another kind, called gamma-iron, appears when iron is very hot. These changes help scientists understand what happens deep inside planets like Earth. Iron can also act like a magnet below a certain temperature, which is why some tools and toys can stick to magnets.

Origin and occurrence in nature

Iron is very common in rocky planets like Earth. This is because it was made during big explosions of stars called type Ia supernovae, which spread iron into space.

A polished and chemically etched piece of an iron meteorite, believed to be similar in composition to the Earth's metallic core, showing individual crystals of the iron-nickel alloy (Widmanstatten pattern)

We find very little pure iron on Earth's surface because it changes when it meets air. But scientists think that Earth's inner and outer core are mostly made of iron mixed with nickel. The moving liquid in the outer core helps create Earth's magnetic field. Other planets like Mercury, Venus, and Mars, as well as our Moon, also likely have iron cores. Some asteroids are thought to be made partly of iron too.

Iron is most common inside Earth, but only about 5% of the Earth's crust is made of iron. In the crust, iron mixes with other elements to make minerals such as hematite, magnetite, and siderite. These minerals are important for getting iron to use in making things. Iron is also found in rocks and can give them colors like red and yellow.

Chemistry and compounds

Iron is a special kind of metal called a transition metal. It can form many different compounds because its atoms can lose different numbers of electrons. One famous iron compound called ferrocene helped scientists learn more about these kinds of chemicals.

Iron mostly forms compounds where it has lost two or three electrons. But it can also lose up to six electrons, as in a bright purple compound called potassium ferrate (K2FeO4). Iron mixes well with other elements to create useful materials. For example, magnetite and Prussian blue are both important in making things like computer parts and blue coloring.

Iron does not mix with mercury, so mercury is stored in iron containers. Pure iron does not rust easily because of a protective layer that forms on its surface.

Oxidation
state
Representative compound
−2 (d10)Disodium tetracarbonylferrate (Collman's reagent)
−1 (d9)Fe
2(CO)2−
8
0 (d8)Iron pentacarbonyl
1 (d7)Cyclopentadienyliron dicarbonyl dimer ("Fp2")
2 (d6)Ferrous sulfate, Ferrocene
3 (d5)Ferric chloride, Ferrocenium tetrafluoroborate
4 (d4)Fe(diars)
2Cl2+
2, FeO(BF4)2
5 (d3)FeO3−
4
6 (d2)Potassium ferrate
7 (d1)[FeO4] (matrix isolation, 4K)
[Fe(H2O)6]2+ + 2 e⇌ FeE0 = −0.447 V
[Fe(H2O)6]3+ + e⇌ [Fe(H2O)6]2+E0 = +0.77 V
FeO2−
4 + 8 H3O+ + 3 e
⇌ [Fe(H2O)6]3+ + 6 H2OE0 = +2.20 V
[Fe(H2O)6]3+⇌ [Fe(H2O)5(OH)]2+ + H+K = 10−3.05 mol dm−3
[Fe(H2O)5(OH)]2+⇌ [Fe(H2O)4(OH)2]+ + H+K = 10−3.26 mol dm−3
2[Fe(H2O)6]3+⇌ [Fe(H2O)4(OH)]4+2 + 2H+ + 2H2OK = 10−2.91 mol dm−3

History

Main article: History of ferrous metallurgy

Iron has been known and used since ancient times. Though it is one of the most common metals on Earth, iron objects are rarer than gold or silver ones because iron easily rusts. It took many years for people to learn how to make tools and weapons from iron instead of bronze.

People first used iron that fell from the sky in meteorites. These pieces of iron contained nickel and were special because they came from space. Ancient people in Egypt made beads from this kind of iron over 5,000 years ago, and a famous dagger made from meteorite iron was found in the tomb of a king named Tutankhamun. Later, people learned how to get iron from rocks, called ores, and this led to a time known as the Iron Age.

From this discovery, iron spread around the world. It was used in many places, including India, Greece, and China. During a time called the Industrial Revolution, new ways of making iron were invented, which helped build bridges, trains, and many other important things we still use today.

Symbolic role

Iron has played an important role in stories and traditions. Ancient Greek poets, like Hesiod, described different ages of humans using the names of metals, including the Iron Age. This period was linked with Rome and was described as a time when people faced many difficulties.

During the German Campaign of 1813, King Frederick William III created the first Iron Cross as an award for brave soldiers. At that time, people in Berlin were encouraged to give their gold and silver jewellery to help fund the war effort, showing their support by turning precious metals into iron.

Production of metallic iron

The industrial production of iron or steel has two main steps. First, iron ore is mixed with coke in a blast furnace. This process creates pig iron, which has a lot of carbon. In the second step, the carbon level is lowered to make steel or cast iron. This is done by adding or removing certain materials.

There are other ways to make iron, such as using natural gas to create a softer form of iron called sponge iron, or using a special reaction with aluminium powder called the thermite process. Scientists are also studying a method called molten oxide electrolysis, which could make iron without releasing harmful gases.

Iron production 2009 (million tonnes)
CountryIron orePig ironDirect ironSteel
China1,114.9549.4573.6
Australia393.94.45.2
Brazil305.025.10.01126.5
Japan66.987.5
India257.438.223.463.5
Russia92.143.94.760.0
Ukraine65.825.729.9
South Korea0.127.348.6
Germany0.420.10.3832.7
World1,594.9914.064.51,232.4

Applications

Iron is one of the most commonly used metals, making up over 90% of all metal produced around the world. It is strong and inexpensive, which makes it perfect for building things like machine tools, rails, automobiles, ship hulls, and even the frameworks of buildings. Because pure iron is soft, it is usually mixed with other elements to create steel, which is much stronger.

Iron and its alloys have many important uses. Different types of steel are made by adding small amounts of other elements, which change the steel’s properties. Some steels are very strong but also expensive, so they are used only when needed. Iron is also used in chemistry for certain reactions and in making important materials like paints and medicines. However, iron can rust when it gets wet, so people use methods like painting or special coatings to protect it.

Characteristic values of tensile strength (TS) and Brinell hardness (BH) of various forms of iron.
MaterialTS
(MPa)
BH
(Brinell)
Iron whiskers11000
Ausformed (hardened)
steel
2930850–1200
Martensitic steel2070600
Bainitic steel1380400
Pearlitic steel1200350
Cold-worked iron690200
Small-grain iron340100
Carbon-containing iron14040
Pure, single-crystal iron103

Biological and pathological role

Iron is very important for living things. It helps in making special clusters called iron–sulfur clusters, which are part of enzymes that help plants turn air into useful substances. Iron is also found in proteins that carry and store oxygen in our bodies. These proteins help move oxygen from our lungs to the rest of our body.

The human body contains a small amount of iron, mostly in a substance called hemoglobin, which carries oxygen in our red blood cells. Our bodies carefully manage iron levels by recycling it and controlling how much we take in from food.

Iron is found in many foods such as red meat, oysters, beans, and leaf vegetables. Most people get enough iron from their diet, but some, like growing teens and women who can have babies, need more. Too little iron can cause health problems, while too much can also be harmful. Doctors can help figure out if someone needs more or less iron.

Images

A scientific diagram showing the emission spectrum of the element iron, used to study light patterns in chemistry and physics.
A scientific graph showing how different types of radiation interact with iron, useful for learning about physics and materials.
A beautiful natural trail in Roussillon, France, showing colorful ochre cliffs and pathways.
A sample of Iron(II) oxide, a black powder used in various industrial applications.
A close-up view of iron(III) oxide, a common iron compound often used in industry and science.
A sample of iron oxide, also known as magnetite, a naturally occurring chemical compound.
A sample of iron(II) sulfate heptahydrate, a blue-green crystalline compound often used in chemistry experiments and education.
A colorful scientific model showing the arrangement of atoms in an iron crystal structure.
A scientific image showing a chemical test for iron using a coordination compound, useful for learning about chemistry and laboratory procedures.
A stunning view of layered rock formations formed millions of years ago in a Minnesota state park.
A sample of Iron(III) chloride hexahydrate, a common inorganic compound often used in chemistry experiments and industrial processes.
A scientific comparison of two chemical solutions: sodium ferrate on the left and permanganate on the right.

Related articles

This article is a child-friendly adaptation of the Wikipedia article on Iron, available under CC BY-SA 4.0.

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