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Wave function

Adapted from Wikipedia · Discoverer experience

Visualizations showing where you might find an electron around a hydrogen atom at different energy levels. Brighter areas mean the electron is more likely to be there.

In quantum physics, a wave function is a mathematical way to describe the state of a tiny system, like an atom or a particle. We usually write it using the Greek letter ψ (psi). It helps us understand how these small parts of nature behave.

Quantum harmonic oscillators for a single spinless particle. The oscillations have no trajectory, but are instead represented each as waves; the vertical axis shows the real part (blue) and imaginary part (red) of the wave function. Panels A–D show four different standing-wave solutions of the Schrödinger equation. Panels E–F show two different wave functions that are solutions of the Schrödinger equation but not standing waves.

Wave functions can be added together and changed by numbers to make new ones. They act a bit like water waves or waves on a string because they follow rules similar to those waves. This is why they are called "wave" functions.

A wave function uses special numbers called complex numbers, and these help us find the chances of finding a particle in different places. To get real chances, we use a rule called the Born rule. This tells us how likely it is to find a particle somewhere by looking at the wave function in that spot.

Historical background

In 1900, Max Planck discovered that the energy of a photon relates to its frequency. In 1916, he also found a link between a photon's momentum and its wavelength. In 1923, De Broglie suggested that this same idea might apply to particles with mass, which helped start modern quantum mechanics.

During the 1920s and 1930s, scientists used math to develop quantum mechanics. Some, like Louis de Broglie and Erwin Schrödinger, used calculus and created what is called "wave mechanics." Others, like Werner Heisenberg and Max Born, used linear algebra and developed "matrix mechanics." Schrödinger later showed that both methods gave the same results.

In 1926, Schrödinger created an important equation named after him. This equation helps describe how particles behave in quantum systems. At first, people thought the wave functions showed where particles were spread out, but this didn’t match experiments. In 1926, Max Born suggested that wave functions relate to the chances of finding a particle in different places, which is part of how quantum mechanics is understood today.

Definition (one spinless particle in one dimension)

The wave function is a key idea in quantum physics. It describes the state of a tiny particle, like an atom or a photon. We often use the Greek letter ψ (psi) to represent the wave function.

In quantum mechanics, wave functions can be combined in different ways to create new ones. This helps scientists understand how particles behave in various situations.

For a simple case of a single particle moving along a straight line, the wave function tells us the probability of finding the particle at a certain position. By squaring the wave function, we get a number that shows how likely the particle is to be in any specific spot.

This idea helps explain many strange behaviors of tiny particles and is important for understanding the world of quantum physics.

Definitions (other cases)

In quantum physics, a wave function describes the state of a quantum system. It uses special math to show how particles behave in ways that are different from everyday objects.

Wave functions can be combined in certain ways to create new descriptions of quantum systems. This helps scientists understand complex situations where particles act together. The math behind this creates a space called a Hilbert space, which is important for studying quantum mechanics.

Time dependence

Main article: Dynamical pictures

In quantum physics, for systems where the forces don’t change with time, the wave function can be described as a mix of the system’s positions and a special part that changes with time. This special part follows a rule called the Schrödinger equation. When we look at many particles, their wave function shows how their positions and this time-changing part work together. These special types of wave functions are known as stationary states.

Quantum states and their properties can be described in different ways. In one way, called the Schrödinger picture, the state changes with time while the properties stay the same. In another way, called the Heisenberg picture, the state stays the same while the properties change with time. There is also a middle way that uses both changing states and changing properties, which helps in calculating certain results.

Non-relativistic examples

Quantum physics uses special math ideas called wave functions to describe tiny particles. These wave functions show how particles behave in different situations.

Scattering at a finite potential barrier of height V0. The amplitudes and direction of left and right moving waves are indicated. In red, those waves used for the derivation of the reflection and transmission amplitude. E > V0 for this illustration.

One important example is when a particle meets a barrier. Even if the barrier seems too strong to cross, the particle can still reach it in ways that surprise us. Another example is the quantum harmonic oscillator, where particles move back and forth in a special pattern. We can describe these patterns using math shapes called Hermite polynomials.

We also study electrons in hydrogen atoms. Here, the wave functions help us understand how electrons are arranged around the atom. These patterns are shown using special math shapes called spherical harmonics and Laguerre polynomials. The hydrogen atom is special because we can solve its wave functions exactly using these methods.

Wave functions and function spaces

In quantum physics, a wave function describes the state of a tiny system, like an atom or a particle. We use special math symbols, like ψ or Ψ, to write about these wave functions.

Wave functions can be combined in certain ways to make new ones. This helps us understand how different states can work together in the rules of quantum physics.

The math that describes these wave functions fits into special sets called function spaces. These spaces help scientists work with the wave functions in a structured way. One important type is called a Hilbert space, which is very useful for solving problems in quantum physics.

More on wave functions and abstract state space

Main article: Quantum state

In quantum physics, all the possible ways a system can be described are grouped together in a special mathematical space. This space is called a Hilbert space. Because there are many ways to describe this space, scientists talk about an abstract version called "state space." In this space, each possible state of the system is shown as a vector.

One important idea is that the wave function tells us the chance of finding the system in a particular state. This wave function is part of the vector that represents the system's state. The wave function helps us understand how likely we are to find the system in different conditions.

Ontology

Main article: Interpretations of quantum mechanics

People have wondered for a long time whether the wave function is real or just a way to describe what we know about something. Famous scientists like Erwin Schrödinger, Albert Einstein, and Niels Bohr thought deeply about this. Some believed the wave function shows what we know, while others thought it was a real part of nature. Einstein felt that real descriptions of nature should be about space and time, not just abstract ideas.

Images

Animation showing how a wave function spreads out over time, illustrating a key idea in quantum physics.
An illustration representing quantum dots, tiny particles used in science and technology.

Related articles

This article is a child-friendly adaptation of the Wikipedia article on Wave function, available under CC BY-SA 4.0.

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